Übersicht			Auf mobile öffnen

Lieferstatus:	i.d.R. innert 7-14 Tagen versandfertig
Veröffentlichung:	August 2013
Genre:	Naturwissensch., Medizin, Technik
	C / Catalysis / Chemical Engineering / Chemistry and Materials Science / Environmental Chemistry / Industrial Chemistry / Industrial chemistry & chemical engineering / Industrial Chemistry/Chemical Engineering / Physical Chemistry / Pollution & threats to the environment
ISBN:	9783642391149
EAN-Code:	9783642391149
Verlag:	Springer Berlin Heidelberg
Einband:	Kartoniert
Sprache:	English
Serie:	SpringerBriefs in Green Chemistry for Sustainability SpringerBriefs in Molecular Science
Dimensionen:	H 235 mm / B 155 mm / D 8 mm
Gewicht:	219 gr
Seiten:	136
Zus. Info:	Paperback
Bewertung:	Titel bewerten / Meinung schreiben

Inhalt:

This book provides a comprehensive review of a new generation of selective oxidation titanosilicate catalysts with the MWW topology (Ti-MWW) based on the research achievements of the past 12 years. It gives an overview of the synthesis, structure modification and catalytic properties of Ti-MWW. Ti-MWW can readily be prepared by means of direct hydrothermal synthesis with crystallization-supporting agents, using dual-structure-directing agents and a dry-gel conversion technique. It also can be post-synthesized through unique reversible structure transformation and liquid-phase isomorphous substitution. The structural conversion of Ti-MWW into the materials usable for processing large molecules is summarized. Taking advantage of the structure diversity of the lamellar precursor of Ti-MWW, it can be fully or partially delaminated, and undergo interlayer silylation to obtain a novel structure with larger porosity. In the selective oxidation (alkene epoxidation and ketone/aldehyde ammoximation) with hydrogen peroxide or organic peroxide as an oxidant, the unique catalytic properties of Ti-MWW are described in comparison to conventional titanosilicates such as TS-1 and Ti-Beta.