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Integration of Innovative Oxide Materials in an IT-SOFC: Elaboration and electrochemical characterisations of planar anode-supported Solid Oxide Fuel
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(Buch) |
Dieser Artikel gilt, aufgrund seiner Grösse, beim Versand als 2 Artikel!
| Inhalt: |
| This book aimed at assessing the potential of a novel cathode / electrolyte couple for IT-SOFC applications (700°C), through the elaboration and testing of planar anode-supported cells. The materials involved were the perovskite-structured BaIn0.3Ti0.7O2.85 (BIT07) electrolyte and the rare earth nickelate Ln2-xNiO4+delta (LnN, Ln = La, Nd, Pr) cathodes, both materials having shown promising properties in preliminary work done at the IMN and the ICMCB, respectively. The first part of this work concerned the implementation of a cell elaboration protocol using low-cost and scalable shaping techniques (cell size 3 x 3 cm2); namely, the Ni / BIT07 anodes were elaborated by tape casting, the BIT07 electrolyte by vacuum slip casting and the cathodes by screen printing. Comparison of electrochemical results for a first and second generation of cells highlighted the usefulness of adding a GDC buffer layer in between the LnN cathodes and the BIT07 electrolyte. A competitive polarisation resistance of 0.29 Ohm cm² has been obtained at 700°C and 0.7V with a GDC | PrN cathode. This cell has been operated beyond 500 hours. |
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i.d.R. innert 7-14 Tagen versandfertig
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